New insight into atmospheric alteration of alkali-lime silicate glasses
Type de document : Archive ouverte
| ISSN: 0010-938X
Auteur(s) : Alloteau, Fanny | Lehuédé, Patrice | Majérus, Odile | Biron, Isabelle | Dervanian, Anaïs | Charpentier, Thibault | Caurant, Daniel
Edité par HAL CCSD ; Elsevier
- Type de document
- info:eu-repo/semantics/article ; Journal articles
- Langue
- en
- Date de publication
- 2017-03-30
- Résumé
- International audience.
A mixed alkali lime silicate glass altered in atmospheric conditions (80 °C/85%RH, Relative Humidity) for various lengths of time was characterized at all scales. The altered glass forms a hydrated solid phase bearing about 10 wt% of H 2 O in the form of Si-OH groups and molecular water. No alkali depletion was observed after ageing tests. Structural results from 1 H, 23 Na and 29 Si MAS NMR point out the close proximity of Si-OH, H 2 O and Na + species. This study gives new insight into the mechanisms of the atmospheric alteration, essential to conservation strategies in industry and cultural heritage.
- Citer la référence
- Alloteau, Fanny , Lehuédé, Patrice , Majérus, Odile , Biron, Isabelle , Dervanian, Anaïs , Charpentier, Thibault , Caurant, Daniel, New insight into atmospheric alteration of alkali-lime silicate glasses, HAL CCSD,